Gnome does not pass the Superkey ("Windows"-key) through to Citrix app in newer versions.
There is a setting which corrects this issue:
gsettings set org.gnome.mutter.wayland xwayland-grab-access-rules "['Wfica']"
gsettings set org.gnome.mutter.wayland xwayland-allow-grabs true
gsettings set org.gnome.mutter.wayland xwayland-allow-grabs true
You can remoe this with setting with
gsettings reset org.gnome.mutter.wayland xwayland-grab-access-rules
gsettings reset org.gnome.mutter.wayland xwayland-allow-grabs
gsettings reset org.gnome.mutter.wayland xwayland-allow-grabs